I. 서론

II. 열역학 제 1, 2, 3 법칙

III. 상태, 상태변수 그리고 프로세스

IV. 기체의 거동

IV-1 Boyle-Charles Gas Law

IV-2 van der Waals Equation

IV-3 Internal Energies of Ideal Gas and Real Gas

V. 상태 변화 과정과 열용량

V-1 Processes of Ideal Gas

i) 등체적과정 (Constant Volume Process)

ii) 등압과정 (Constant Pressure Process)

iii) 단열과정 (Adiabatic Process)

iv) 등온과정 (Isothermal Process)

V-2 Heat Capacity

V-3 Enthalpy, H

V-4 Temperature Change during an Adiabatic Process

VI. 엔트로피의 통계역학적 해석

VI-1 Definition of Entropy S

VI-2 Statistical Interpretation of Entropy

VI-3 Thermal Entropy and Configurational Entropy

VI-4 Boltzmann Distribution Function

VI-5 Proof of lnΩ being proportional to Clausius Entropy S

VII. 가역과정과 비가역과정

VII-1 Irreversible Process

VII-2 Entropy of Irreversible Processes

VIII. 보조함수

VIII-1 Geometric Relations

VIII-2 Auxiliary Functions

(1) Enthalpy

(2) Helmholtz Free Energy

(3) Gibbs Free Energy

VIII-3 Differentials of Auxiliary Functions

VIII-4 Maxwell Relations

VIII-5 Applications of Maxwell Relation using Experimentally determined Parameters

IX. 엔탈피와 엔트로피 함수 그리고 Gibbs 자유에너지

IX-1 Enthalpy as a function of Temperature under a constant Pressure

IX-2 Entropy as a function of Temperature under a constant Pressure

IX-3 Gibbs Free Energy as a function of Temperature under a constant Pressure

IX-4 Phase Diagram determined from Gibbs Free Energy Change with Temperature and Pressure

IX-5 Clapeyron Equation

IX-6 Clausius-Clapeyron Equation

X. 기체의 거동

X-1 Temperature Variation by Heat Transfer under constant Pressure

X-2 Pressure Variation by Work Transfer under constant Temperature

X-3 van der Waals Gas Model describing Real Gas Behavior

XI. 혼합 기체의 거동

XI-1 Gibbs Free Energy Variation with Pressure under constant Temperature

XI-2 Mixture of Ideal Gases

XI-3 Partial Molar Quantities and their Physical Meanings

XI-4 Chemical Potential as a Partial Molar Quantities

XI-5 Equilibrium Vapor Pressure of a Component in Condensed Solutions

XI-6 Activity and Activity Coefficient

XI-7 Raoult's Law and Henry's Law

XI-8 Chemical Potential and Activity

XII. 화학반응 평형

XII-1 Reactions involving Gases

XII-2 Effect of Temperature on Chemical Reaction Equilibrium

XII-3 Reference Pressure and Effect of Total Pressure on Chemical Reactions

XII-4 Reactions involving Pure Condensed Phases and a Gaseous Phase

(1) CO/CO2 비율 조절을 이용한 산소분압 조절

(2) H2/H2O 비율 조절을 이용한 산소분압 조절

XII-5 Reactions involving Condensed Solution Phases and a Gaseous Phase

XIII. 상태도

XIII-1 Free Energy Change as a Solute dissolving into a Matrix

XIII-2 Gibbs Free Energy of a Binary System

XIII-3 Ideal Solution

XIII-4 Development of Phase Diagrams

XIII-5 Development of Eutectic Phase Diagrams

XIII-6 Development of Other Phase Diagrams

XIV. 용액모델

XIV-1 Non-ideal Mixing

XIV-2 Regular Solution Model

XV. 전기화학

XV-1 Ionization Energy of an Element

XV-2 Equilibrium in Two Phase Systems involving an Electrolyte

XV-3 Equilibrium in an Electrochemical Cell

XV-4 Standard Hydrogen Electrode

XV-5 Pourbaix Diagram

(1) The Stability of Water

(2) Pourbaix Diagram for Copper